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Isostructural species are those which have the same shape and hybridization. Among the given species identify the isostructural pairs. 

(a) [NF3 and BF3]
(b) [BF4andNH+4]
(c) [BC13 and BrCl3]                           
(d) [NH3 and NO3 ]

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The best answer for Isostructural species is those which have the same shape and hybridization.

(b) NF3 is pyramidal whereas BFis planar triangular.
BF4 and NH+4 ions both are tetrahedral.
BC13 is triangular planar whereas BrCl3 is pyramidal.
NH3 is pyramidal whereas N03 is triangular planar.

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